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40 New Anniversary Oil Colours - Now Available Explore Collections

Michael Harding
All Pigments
Colour Index Code

PW4

Zinc White

Chemistry
Zinc oxide (ZnO)
Origin
Synthetic mineral.
History
Introduced c.1780; transparent, slow-drying, and non-yellowing.
Toxicity
Non-toxic.

Zinc White (PW4) is Zinc oxide (ZnO).

Lightfastness
Excellent
PW4: Questions & Answers

What is PW4?

PW4 (Zinc White) is Zinc oxide (ZnO). Synthetic mineral..

What is the chemistry of PW4?

PW4 is Zinc oxide (ZnO).

Is PW4 toxic?

Non-toxic.

Is PW4 lightfast?

In the Michael Harding range, colours using PW4 are rated excellent for lightfastness.

Which Michael Harding colours use PW4?

PW4 appears in 16 Michael Harding colours: Zinc White (Withdrawn), Chinese White, Warm White, Warm Light Yellow, Warm Yellow, Brilliant Pink and 10 more.

Pigment History

The story of PW4

Valued for transparency, slow drying and a lack of yellowing - the white of choice for pale tints and delicate glazes.

How it is made

Zinc oxide is produced by burning zinc in air and collecting the oxide fume. Milled into oil it gives a transparent, slow-drying, non-yellowing white - often blended with titanium to balance opacity with flexibility.

In the hands of the masters

A late arrival, zinc white was taken up by the Impressionists for clean, non-toxic tints and by 19th-century watercolourists; Turner was among the early adopters.

Origin
Synthetic mineral - zinc oxide, introduced as a painter’s white c.1780.
Chemistry
Zinc oxide (ZnO), a synthetic inorganic white.

Michael Harding colours using PW4

16 colours across both rangesLightfastness: Excellent

Watercolours containing PW4

15 colours
Michael Harding colours containing PW4, with medium, transparency, lightfastness and granulation. Granulation applies to watercolour only.
ColourMediumTransparencyLightfastnessGranulation
Zinc White (Withdrawn)
No. 103
OilSemi-OpaqueExcellent—
Chinese White
W103
WatercolourSemi-OpaqueExcellentNO
Warm White
W102
WatercolourSemi-OpaqueExcellentNO
Warm Light Yellow
W104
WatercolourSemi-OpaqueExcellentNO
Warm Yellow
W105
WatercolourSemi-OpaqueVery GoodNO
Brilliant Pink
W207
WatercolourSemi-OpaqueExcellentNO
Blue Verditer
W233
WatercolourSemi-TransparentExcellentYES
Sky Blue (Phthalo)
W114
WatercolourSemi-TransparentExcellentNO
Pale Violet
W149
WatercolourSemi-OpaqueExcellentYES
Kings Blue Deep
W142
WatercolourOpaqueExcellentYES
Kings Blue Light
W141
WatercolourOpaqueExcellentYES
Vivid Blue
W143
WatercolourOpaqueExcellentNO
Phthalocyanine Turquoise
W140
WatercolourOpaqueExcellentNO
Permanent Green Light
W145
WatercolourOpaqueVery GoodNO
Emerald Green
W146
WatercolourOpaqueExcellentYES
Neutral Grey (N5)
W136
WatercolourOpaqueExcellentYES
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Mix with

Complementary pigments to mix with PW4

Opposite-family pigments that pair cleanly with PW4 for neutrals, shadows and chromatic greys.

Open the Mixing Studio →

Product Information & Disclaimer

The information provided on this website is based on research and testing conducted by Michael Harding Art Formulas Ltd and is intended as general guidance on the characteristics and potential uses of our products in established painting practices.

While we take care to provide accurate and reliable information, individual materials, techniques, working conditions and applications can vary. Michael Harding Art Formulas Ltd cannot guarantee that any product will be suitable for every individual purpose or application. Users should carefully read all product labels, instructions and safety information and carry out appropriate testing before use, particularly when developing individual techniques or combining materials.

To the fullest extent permitted by applicable law, Michael Harding Art Formulas Ltd makes no express or implied warranties as to merchantability or fitness for a particular purpose and accepts no liability for any loss or damage, including indirect or consequential loss, arising from the use or application of its products.

Colour Representation

Colours displayed on this website and in printed materials are for guidance only. Their appearance may vary depending on screen settings, device, lighting conditions, printing processes and other factors, and may therefore differ from the appearance of the physical product.

For the most accurate representation of colour, texture and finish, we strongly recommend viewing a physical product sample or swatch in person before making a final selection or purchase. Where colour accuracy is important, please do not rely solely on digital or printed representations.

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